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ممكن حل اسأله كتاب serway |
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![]() 1. A crystalline solid consists of atoms stacked up in a repeating
lattice structure. Consider a crystal as shown in Figure P1.1a. The atoms reside at the corners of cubes of side L $ 0.200nm. One piece of evidence for the regular arrangement of atoms comes from the flat surfaces along which a crystal separates, or cleaves, when it is broken. Suppose this crystal cleaves along a face diagonal, as shown in Figure P1.1b. Calculate the spacing d between two adjacent atomic planes that separate when the crystal cleaves. Measurement Section 1.3 Density and Atomic Mass 2. Use information on the endpapers of this book to calculate the average density of the Earth. Where does the value fit among those listed in Tables 1.5 and 14.1? Look up the density of a typical surface rock like granite in another source and compare the density of the Earth to it. 3. The standard kilogram is a platinum–iridium cylinder 39.0 mm in height and 39.0 mm in diameter. What is the density of the material? 4. A major motor company displays a die-cast model of its first automobile, made from 9.35 kg of iron. To celebrate its hundredth year in business, a worker will recast the model in gold from the original dies. What mass of gold is needed to make the new model? 5. What mass of a material with density & is required to make a hollow spherical shell having inner radius r 1 and outer radius r 2? 6. Two spheres are cut from a certain uniform rock. One has radius 4.50 cm. The mass of the other is five times greater. Find its radius. 7. Calculate the mass of an atom of (a) helium, (b) iron, and (c) lead. Give your answers in grams. The atomic masses of these atoms are 4.00 u, 55.9 u, and 207 u, respectively. 8. The paragraph preceding Example 1.1 in the text mentions that the atomic mass of aluminum is 27.0u $ 27.0 ! 1.66 ! 10"27 kg. Example 1.1 says that 27.0 g of aluminum contains 6.02 ! 1023 atoms. (a) Prove that each one of these two statements implies the other. (b) What If ? What if it’s not aluminum? Let M represent the numerical value of the mass of one atom of any chemical element in atomic mass units. Prove that M grams of the substance contains a particular number of atoms, the same number for all elements. Calculate this number precisely from the value for u quoted in the text. The number of atoms in M grams of an element is called Avogadro’s number NA. The idea can be extended: Avogadro’s number of molecules of a chemical compound has a mass of M grams, where M atomic mass units is the mass of one molecule. Avogadro’s number of atoms or molecules is called one mole, symbolized as 1 mol. A periodic table of the elements, as in Appendix C, and the chemical formula for a compound contain enough information to find the molar mass of the compound. (c) Calculate the mass of one mole of water, H2O. (d) Find the molar mass of CO2. 9. On your wedding day your lover gives you a gold ring of mass 3.80 g. Fifty years later its mass is 3.35 g. On the average, how many atoms were abraded from the ring during each second of your marriage? The atomic mass of gold is 197 u. 10. A small cube of iron is observed under a microscope. The edge of the cube is 5.00 ! 10"6 cm long. Find (a) the mass of the cube and (b) the number of iron atoms in the cube. The atomic mass of iron is 55.9 u, and its density is 7.86 g/cm3. 11. A structural I beam is made of steel. A view of its crosssection and its dimensions are shown in Figure P1.11. The density of the steel is 7.56 ! 103 kg/m3. (a) What is the mass of a section 1.50 m long? (b) Assume that the atoms are predominantly iron, with atomic mass 55.9 u. How many atoms are in this section? 15.0 cm 1.00 cm 1.00 cm 36.0 cm Figure P1.11 12. A child at the beach digs a hole in the sand and uses a pail to fill it with water having a mass of 1.20 kg. The mass of one molecule of water is 18.0 u. (a) Find the number of water molecules in this pail of water. (b) Suppose the quantity of water on Earth is constant at 1.32 ! 1021 kg. How many of the water molecules in this pail of water are likely to have been in an equal quantity of water that once filled one particular claw print left by a Tyrannosaur hunting on a similar beach? Section 1.4 Dimensional Analysis The position of a particle moving under uniform acceleration is some function of time and the acceleration. Suppose we write this position s $ ka mt n, where k is a dimensionless constant. Show by dimensional analysis that this expression is satisfied if m $ 1 and n $ 2. Can this analysis give the value of k? 14. Figure P1.14 shows a frustrum of a cone. Of the following mensuration (geometrical) expressions, which describes (a) the total circumference of the flat circular faces (b) the volume (c) the area of the curved surface? (i) #(r 1 ' r 2)[h2 ' (r 1 " r 2)2]1/2 (ii) 2#(r 1 ' r 2) (iii) #h(r 1 2 ' r 1r 2 ' r 2 2). 13. |
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